zaboleti

1. (of a body part) to start to hurt; to start aching
   Posle ručka me je zabolela glava. — After lunch my head started to hurt.
   Zabolela su me leđa od sedenja. — My back started hurting from sitting.
2. (of words, actions) to hurt; to wound; to upset
   Njegove reči su je jako zabolele. — His words hurt her a lot.

The person who feels the pain is in the accusative: zabolela me glava.