naslikati

1. to paint
   Ovu sliku je naslikala moja baka. — My grandmother painted this picture.
   Naslikao je portret svoje žene. — He painted a portrait of his wife.
2. (in words) to depict; to paint a picture of
   U knjizi je verno naslikao život na selu. — In the book he faithfully depicted village life.

For taking a photo, uslikati or slikati is usually used.